He's a bit arrogant but
In any relationship, whatever irritates you at the outset has the potential to become a real source of resentment later, so be clear about where your boundaries are.
A lot depends on how much work this potential partner is proposing to put in before bringing in the big bucks and potentially cashing out. But putting all those meta considerations aside, if you want 30%, he wants 40%, and you really feel he has something you don't which would be hard to find elsewhere, 33 1/3% seems like the natural inflection point.
If you think he’s overvaluing himself, showing him the door is the best way to communicate that
30% is too rich IMO. There's no correct answer so I doubt you'll be able to get one. Given that the co-founder is someone you just met, not a long time acquaintance or friend that you know you can work well with and you know their skills, I would simply look for another co-founder. There is a YC matching program if you want to do that.